Henry Cejudo became the first Olympic champion to win a UFC belt in the UFC history. Cejudo beat the defending champion, Demetrious Johnson in UFC 227 in Los Angeles.
Which UFC champions have been medal winners in the Olympics?
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Looking at UFC after introduction of weight classes, here is the list of UFC champions I found to have also won an Olympics medal:
Ronda Rousey was a UFC Champion and has a bronze medal in judo.